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Journal Articles

Selective OD bond dissociation of HOD; Photodissociation of vibrationally excited HOD in the 5$$nu$$$$_{OD}$$ state

Akagi, Hiroshi; Fukazawa, Hiroshi; Yokoyama, Keiichi; Yokoyama, Atsushi

Journal of Chemical Physics, 123(18), p.184305_1 - 184305_7, 2005/11

 Times Cited Count:21 Percentile:57.25(Chemistry, Physical)

Vibrationally excited HOD in the fourth overtone state of the OD-stretching mode (5$$nu$$$$_{OD}$$) has been photodissociated by ultraviolet photolysis at ca. 243.1 nm. Branching ratio between the OH- and OD-bond dissociation channels has been determined by detecting the H and D atoms. The OD-bond dissociation is the dominant channel, with the yield of H atom generated by the photolysis being below the detection limit.

Journal Articles

Bond-selective photodissociation of partially deuterated ammonia molecules; Photodissociations of vibrationally excited NHD$$_{2}$$ in the 5$$nu$$$$_{NH}$$ state and NH$$_{2}$$D in the 5$$nu$$$$_{ND}$$ state

Akagi, Hiroshi; Yokoyama, Keiichi; Yokoyama, Atsushi

Journal of Chemical Physics, 120(10), p.4696 - 4704, 2004/03

 Times Cited Count:19 Percentile:52.95(Chemistry, Physical)

no abstracts in English

Journal Articles

Photodissociation of highly vibrationally excited NH$$_{3}$$ in the 5$$nu_{N-H}$$ region; Initial vibrational state dipendence of N-H bond dissociation cross section

Akagi, Hiroshi; Yokoyama, Keiichi; Yokoyama, Atsushi

Journal of Chemical Physics, 118(8), p.3600 - 3611, 2003/02

 Times Cited Count:29 Percentile:67.38(Chemistry, Physical)

no abstracts in English

JAEA Reports

None

*; Miyamoto, Shuji*; *; *; *; Hasegawa, Makoto; Yamazaki, Yoshio

JNC TY9400 2000-008, 20 Pages, 2000/03

JNC-TY9400-2000-008.pdf:0.81MB

no abstracts in English

Journal Articles

Algebraic-eikonal approach to the electron-molecule-collision process; Vibrational excitation and quadrupole interaction

A.Mengoni*; Shirai, Toshizo

Physical Review A, 44(11), p.7258 - 7268, 1991/12

 Times Cited Count:9 Percentile:52.54(Optics)

no abstracts in English

Journal Articles

Negative ions, Formation and properties

Oyo Butsuri, 49(1), p.52 - 60, 1980/00

no abstracts in English

Oral presentation

Computer simulation of isotope-selective vibrational excitation of lithium chloride molecules by optical pulses

Ichihara, Akira

no journal, , 

We explored the pulse shape to excite the vibrational states of diatomic molecules whose rotational states were excited isotope-selectively by a terahertz pulse train. Computer simulations based on the coupled-channel method were performed using the gaseous $$^{7}$$Li$$^{35}$$Cl and $$^{7}$$Li$$^{37}$$Cl ensembles in 70 K. The isotope-selective vibrational excitation was investigated using the pulse which has a quasi-rectangle or the Gaussian spectrum. The results indicated that the isotope-selective vibrational excitation can be induced effectively by specifying the spectral frequency range referring to the transition frequencies in the P- and R-branches of molecules. The P-branch transition plays an important role on the excitation in low vibrational states, and both the P- and R-branch transitions contribute to the excitation in high vibrational states.

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